Copolymer?Templated Nickel Oxide for High?Efficiency Mesoscopic Perovskite Solar Cells in Inverted Architecture

نویسندگان

چکیده

Despite the outstanding role of mesoscopic structures on efficiency and stability perovskite solar cells (PSCs) in regular (n–i–p) architecture, PSCs inverted (p–i–n) architecture have rarely been reported. Herein, an efficient stable NiOx (mp-NiOx) scaffold formed via a simple low-cost triblock copolymer template-assisted strategy is employed, this mp-NiOx film utilized as hole transport layer (HTL) PSCs, for first time. Promisingly, approach allows fabrication homogenous, crack-free, robust 150 nm thick HTLs through facile chemical approach. Such high-quality templated structure promotes growth yielding better surface coverage enlarged grains. These desired structural morphological features effectively translate into improved charge extraction, accelerated transportation, suppressed trap-assisted recombination. Ultimately, considerable 20.2% achieved with negligible hysteresis which among highest efficiencies based so far. Moreover, devices indicate higher long-term under ambient conditions compared to planar devices. Overall, these results may set new benchmarks terms performance employing films highly efficient, stable, easy fabricated HTLs.

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ژورنال

عنوان ژورنال: Advanced Functional Materials

سال: 2021

ISSN: ['1616-301X', '1616-3028']

DOI: https://doi.org/10.1002/adfm.202102237